In dense and ordered atomic arrays, destructive interference in photon emission leads to the emergence of subradiant states, which are protected from radiative decay and are characterized by long lifetimes. Within linear optics, subradiant states of one-dimensional chains can be interpreted as guided modes. Collective interactions in arrays have attracted a lot of interest recently, with work showing that collective emission can be used to realize improved quantum memories as well as almost-perfect atomic mirrors, among other exciting applications. While tantalizing, these ideas strongly rely on one assumption: that atoms are two-level systems and only have a unique electronic ground state. However, most atoms exhibit a rich and complex internal structure. In this talk, I will discuss the properties of subradiant states of two-level and multilevel atoms. In particular, I will present a new mechanism for subradiance and atomic wave-guiding in atoms with hyperfine structure, which crucially depends on many-body correlations, a radical departure from conventional subradiant states found in classical-dipole lattices or two-level-atom arrays.